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  • Among the many chemical names of calcium nitride, the one you have probably heard the most is a-calcium nitride, also known as Ca3N2. This material is an inorganic compound with the chemical formula Ca3N2. It has a variety of isomorphic forms and can be used as an alloying agent for other metals.

    A-calcium nitride is the most common form of calcium nitride, and it is produced from fibrous metallic calcium heated to 450 degrees in a purified nitrogen stream. After three to four hours, the calcium is nitrided. This process produces a uniform particle size distribution and high purity.

    Calcium nitride is an important hydrogen storage material. It is commonly used in the production of reactive nitride ions. It can also be used as a reducing agent and a chemical analysis reagent. However, overexposure to this material can lead to skin burns. It is best stored in a dry and cool environment. It should also be kept away from open flames.

    In addition to calcium, nitride also contains nitrogen, sulfur, and fluorine. The nitride ion has a valency of -3. It is a polyatomic ion, or molecular ion.

    The cation comes first in ionic compounds, followed by the anion. In the simple formula, the ionic bond occurs between two opposite charged ions. It is not possible for two p-orbitals to overlap sideways and form a pie bond.

    The ionic bond between the iodine atom and the Pb atom cannot occur. The size of the iodine atom is too large to fit around the Pb atom. Therefore, a PbI4 is not possible.

    Dec 09
    2022
  • Traditionally, Inconel 718 has been produced through vacuum induction melting. However, it has become increasingly popular in the additive manufacturing field. It is used in a variety of engineering applications, including aero engines and liquid fueled rocket components. Its excellent fatigue strength and corrosion resistance make it suitable for these applications.

    In order to analyze the shape, morphology and physico-chemical properties of four states of Inconel 718 powder, FESEM was used. Optical microscopy was also used to examine internal porosity and defects. The images were processed with ImageJ 1.53a software and SEM/BSE to calculate the particle-size distribution.

    The results showed that the hardness of the powder particles did not significantly vary between the powder states. The average hardness of the particles is within the range of 240-250 HV. This value is characteristic of annealed Inconel 718 and statistically insignificant.

    The results show that the average density of the powder is 60%. The bulk density is measured in grams per cubic meter. The apparent density is measured according to the ASTM B212 standard. The tapped density is calculated by dividing the weight of the powder in the cup by its volume.

    The rheological tests include shear test, variable flow rate test, stability test, and wall friction test. The results show that the virgin Inconel powder has good flowability. It is recommended to further optimize the powder for better flowability.

    The results also show that the hardness and the tensile strength of the powder are good. These properties indicate that the current Inconel powder is acceptable for 3D printing. The yield strength of the powder reduces when it is subjected to higher temperatures.

    Dec 09
    2022
  • Graphite Powder

    Graphite powder is a very versatile material that can be used for many purposes. For instance, it can be used as a lubricant and magnetorheological elastomer.

    Graphene nanoflakes

    Graphene nanoflakes are small, flake-like particles of graphite powder. Their average length is five nanometers (nm), ranging from 100 to 200 nm. They can be produced by various solvents, including ionic liquids, surfactants, and hummers. They are used to make transparent conductive electrodes. They are also used in the manufacturing of magnetic elastomers, batteries, brake linings, and crucibles. They have excellent thermal conductivity. These properties make graphene highly interesting for applications in high-performance nanoelectronics and sensors.

    The synthesis of graphene involves two methods. One method is epitaxial growth, which produces a high-crystalline graphene film. The other method is chemical vapor deposition. These processes have different advantages and disadvantages.

    Epitaxial growth is a costly process. Its yield varies by the thickness of the substrate and the quality of the precursors. However, the process is scalable. A recent study demonstrated the transfer printing of macroscopic graphene patterns from patterned HOPG.

    The electrochemical method of producing graphene is simple and environmentally friendly. It does not require hazardous oxidizing materials and can be scaled up easily. It also produces high-quality graphene. The three main advantages of this method are listed in Table 1.

    The process of exfoliation is based on a weak Van der Waals attraction. In order to break the attraction, an external force of 300 nN/mm2 is required. It is also important to keep the graphite layers stable in the medium. A good solvent is important. These solvents should minimize interfacial tension and increase graphene concentration. In addition, ionic liquids can be used as a stable solvent for the graphene. They can be used for green chemistry.

    The electronic properties of graphene are not fully investigated. The reason for this is the difficulty in transfer. The electronic properties of graphene are also limited by the large system sizes. Some researchers have conducted experiments using molecular dynamics to investigate the microscopic origin of friction. The results are promising.

    In addition to the above-mentioned production methods, there are other ways to prepare graphene. Graphene flakes can be made by mechanical exfoliation. It is the cheapest method to produce high-quality graphene. The process is done by a cold wall system, which never heats the walls. This produces a defect-free graphene.

    Magnetorheological elastomers

    Graphite is one of the main components of magnetorheological elastomers (MREs). Various studies have been performed to improve the mechanical and electrical properties of MREs. Graphite is known to enhance the electrical conductivity, increase the initial mechanical properties, and provide a better structure to MREs.

    MREs are mainly fabricated from a polymer matrix. The types of matrix materials used include silicone, natural rubber, and synthetic elastomers. Carbonyl iron particles are usually used as magnetic filler particles. In some cases, these particles are mixed with graphite or graphene particles. These additives can also improve the rheological performance of MR materials.

    Some researchers have developed a coating on the surface of the magnetic particles to improve the interaction between the particles and the matrix medium. This can increase the sedimentation stability of the material. The main deformations of MREs with graphite microparticles are determined by the intensity of the magnetic field. It is important to note that the magnitude of the magnetic field will change the rheological and electric conductivity of the MRE.

    Some of the additives can increase the plasticity of the matrix. In addition to that, these additives can average the distribution of internal stresses in the material. Using silicone oil in the SR matrix can help to create a more homogeneous distribution of CIPs. This can increase the gap between the matrix molecules and reduce the conglutination of the molecules. This results in a better bonding of the CIPs with the rubber matrix.

    In order to produce a more pronounced and dynamic mechanical performance of MR elastomers, graphite particles were introduced into the conventional MREs. In addition to this, carbon black was added to the elastomers. Lastly, a graphite/room temperature vulcanized silicon rubber (Gr-MRE) was fabricated. The properties of the GR/RTV-MRE were analyzed under different magnetic flux densities. The piezoresistive coefficient was also studied.

    The dynamic shear modulus of the isotropic MR elastomers was investigated. This research demonstrated that the storage modulus changes in over 50 percent with the magnetic flux density. Compared to MRE, the relative magnetorheology of the isotropic MR elastomers decreased. In some cases, the zero-field modulus was higher for the hard matrix materials.

    Lithium-graphite intercalation compounds

    Various studies have been carried out to explore the intercalation of alkali metal ions into graphite. However, the mechanisms of insertion are still not well understood.

    A new model of lithium intercalation into graphite is proposed in this work. This model is based on the Daumas-Herold intercalation model. In this model, Li+ ions are inserted into graphite through a series of intermediate stages. The driving force for insertion depends on the mutual distribution of Li atoms. In addition, the model has been predicted for a novel carbon.

    This model is in accordance with the experimental results. The electronic structures of pristine graphites and AB-stacked graphites are shown. The formation energy of a Li-GIC can be estimated from this model. The structure of a graphite electrode was also studied. It was found that a LiC6 compound has a simple hexagonal planar structure. This structure was confirmed by spectroscopic observations.

    The electronic structures of a LiC12 compound show a new ab initio self-consistent-field energy-band structure. The new structure is related to the polarization of the valence orbitals of the graphite atoms. It is also in agreement with the observation of local dislocations in an aged graphite electrode. The crystal structure is a close reflection of the hexagonal mesh of C6. The ionic radius of the Na+ ions in the graphite is large. The ionization energy of the alkali metals decreases with increasing the number of atoms. This favors the electrostatic coupling between the positive ion and the negatively charged graphene.

    In this study, the effect of lithium concentration on the free energy of intercalation was investigated in the graphite structure of a randomly oriented high graphene (ROHG). The effect of Li on the OCV was modeled in a half-cell. The theoretical model was based on the Monte Carlo approach. The enthalpy contribution to the free energy of intercalation was also calculated. This was done in an UB3LYP/6-311G(d) level of theory. The interlayer binding energy and the van der Waals interactions in the graphite lattice are also in good agreement with the experiment.

    This study demonstrates that entropy is associated with the free energy of lithium intercalation in the structure of an experimental carbon. The effects of different lithium compounds on the enthalpy are also seen.

    Graphene powder can be used as a lubricant

    Graphene powder is one of the most promising lubricants. It enjoys exceptional chemical stability. Graphene can be used as a solid lubricant and as a lubricant additive in conventional lubricants. It has unique tribological properties and has potential applications in the field of nano-composite materials. Several studies have been conducted on the anti-wear and antifriction properties of graphene.

    Graphene has superior tribological properties to graphite oxide. It can be used as an additive in lubricants to improve lubrication and antiwear performance. Graphene particles can be produced by supercritical CO2 stripping of graphite. They are stable, crystalline, and do not require continuous heating.

    Chemical modification of graphene can also improve its dispersibility. The modification reduces the out-of-plane flexibility of the molecules. The resulting reduction in adhesive force results in a reduction in the friction coefficient. This is achieved through an increased normal stiffness and bending stiffness.

    The tribological behavior of graphene on steel has been studied at micro-scale. However, recent macro-scale tribological investigations have opened up new avenues for graphene use. These experiments confirmed previous predictions about the tribological properties of graphene.

    In addition to reducing wear, graphene can improve the lubrication of steel. Graphene platelets can be chemically modified to decrease the adhesive force between steel and lubricant. These plates can then be uniformly dispersed in the base oil. The additive concentration is an important factor in reducing the friction and wear of a lubricant. It has been found that 0.075 wt.% of chemically modified graphene provides improved load-carrying capacity. Moreover, it reduced the wear scar diameter of the steel balls by 33%.

    In a study on the lubrication performance of graphene in water, Xie et al. reported that the average wear scar diameter decreased with an increase in the graphene concentration. They also reported that the coefficient of friction (COF) in water is lower than that of the same graphite at room temperature. The friction coefficient is relatively stable when less than 0.15 wt.% is added to a lubricant.

    Despite its low friction, graphite does not provide protection from corrosion. Unlike graphene, graphite does not produce a good thin film coverage.

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    Dec 08
    2022
  • Various investigations on the structural properties of silicon hexaboride have been carried out. They are mainly devoted to the investigation of doped or non-stochiometric SiB6 compounds. Several novel structures were discovered and optimized on the DFT level.

    The amorphous phase of SiB6 has been reported to undergo pressure-induced structural transformation. The high-density amorphous phase consists of differently coordinated motifs and has a pentagonal pyramidal structure. This type of phase has a theoretical bandgap energy of 0.3 eV. It has a relatively low thermal expansion coefficient and high nuclear cross section for thermal neutrons. In addition, it exhibits ductile and semiconducting behavior.

    There are three types of silicon hexaboride modifications: the d-SiB6 type, the g-SiB6 type, and the c-SiB6 type. These types of compounds are distinguished from each other by the degree of atom-atom coordination and the symmetry of the unit cell.

    The d-SiB6 type is characterized by a layered-like structure, whereas the g-SiB6 type shows a cubic symmetry. Both types of compounds have a low thermal expansion coefficient and a moderate melting point. They have a brittle character. In the d-SiB6 type, there are four silicon atoms in six-fold coordination, whereas in the g-SiB6 type, there are five silicon atoms in four-fold coordination.

    Using DFT methods, the d-SiB6-type and g-SiB6-type have been investigated. They have a definite density of states at the Fermi level. This confirms the thermodynamic stability of the compound. It also enables the analysis of the electronic structure of this phase.

    Dec 08
    2022
  • Traditionally, manufacturing methods for metals such as Inconel 718 are based on machining and annealing. However, metallurgists are beginning to turn to metal AM technologies. These new manufacturing processes allow for parts to be created without compromising quality.

    The process of 3D printing Inconel 718 can be used to produce parts that are both functional and cost effective. Inconel has a combination of properties that make it ideal for 3D printing airframe parts. For instance, Inconel's high strength and thermal fatigue resistance make it ideal for use in energy, defense, and aerospace applications.

    The strength of Inconel allows for lightweight components. In addition to its high strength, it also has excellent corrosion resistance. Although Inconel is difficult to machine, it can be 3D printed.

    Inconel 718 is available from many manufacturers around the world. However, it requires additional safety precautions for storage. It must be stored in a controlled atmosphere and the powder must have a stable granulometric composition. If stored incorrectly, the powder will corrode.

    The Inconel 718 research team at Northwestern University is focusing on the development of new tools for enhancing the mechanical properties of the alloy. Their research was recently published in the Procedia Manufacturing journal.

    The team uses 5-axis hybrid machining and 3D printing tools to create thin walls of gas-atomized Inconel 718. The team then applies various post-manufacturing treatments to reduce oxidation and microstructural defects. This will enable the alloy to be 3D printed with mechanical properties closer to conventional manufacturing methods.

    Dec 08
    2022
  • Typically, calcium stearate is used for lubricating properties. However, it also acts as a tack agent and stabilizer. In addition, it is known to have very low toxicity. It can also be used as a mold release agent, especially in pharmaceuticals. It is also used as an anti-caking agent in chemical formulations. It is also a stabilizing agent for PVC resins. In papermaking, calcium stearate emulsion is used to provide a semi-matte gloss to the papers.

    Moreover, it has been used as a drying lubricant for rubbers and as an anti-dusting agent in plastics. It is also used as a water repeater for textiles. In addition, it is used as a release agent for thermosetting plastics. It is also used in cosmetics and pharmaceuticals. It is also used in the construction industry for concrete and other construction materials.

    It can be produced as dust-free granules. It is suitable for pneumatic conveyance. It is also used in injection and extrusion processes. It is widely used in the cement and paper industries. It is also used in the food processing industry.

    It is a white powder that is composed of calcium palmitate and stearic acid. It has a relatively high softening point. It is used in the production of PVC and in various applications in the plastic and rubber industries. It is usually used with mono- and diglycerides. It can also be used as a flavoring agent and a coating agent. It is often used in the food industry as a dough conditioner. It is also used as an anti-dusting agent in a variety of foods. It is also found in feminine hygiene products.

    Dec 08
    2022
  • Various studies have been conducted to evaluate the electrical and optical properties of titanium nitride (TiN) thin films. The most common synthesis method of TiN films is chemical vapor deposition (CVD). In this process, a metallic titanium powder is heated to a high temperature in a nitrogen gas stream. The reaction product is then sinterd to form the final item.

    The conductivity of TiN is generally estimated by four-point probe technique. However, the actual conductivity of TiN depends on the stoichiometry, growth process and post-growth oxidation.

    During the growth process of TiN, residual oxygen and chlorine can play an important role in the growth of the material. In addition, post-growth oxidation can also alter the TiN optical performance. The optical reflectivity of TiN at normal incidence varies significantly depending on the stoichiometry, density, growth process and post-growth oxidation. In this study, X and Y profiles of TiN films were mapped using interferometric confocal microscopy.

    The optical reflectivity of TiN at normal incident angles is mainly dependent on the dielectric losses. In the n-p conduction band, the N-p electrons are dominant and the wide interband absorption originates from states between 2.5 and 5.5 eV below the Fermi level.

    In the d(t2g) conduction band, the N-p-Ti-d(t2g) transition is observed. This transition is in accordance with the selection rules for photonic excitation. The mean free path of the conduction electrons is determined by the grain size.

    It is believed that TiN has similar properties to transparent conduction oxides such as zinc oxide. Thus, it is possible that TiN could serve as a good metallization material in Si technology.

    Dec 08
    2022
  • Having a powder day at Telluride Ski Resort is the dream of any avid skier or snowboarder. Located high in the mountains of southwest Colorado, Telluride's slopes offer great terrain, stunning alpine views, and some of the best natural refrigerators in Colorado.

    The powder stashes can be found in low-angled trees along Silver Tip, Alta, and Henrys. Powder days require a quick action to snag a spot. Getting stuck in too-deep pow is no fun.

    Telluride's lift infrastructure is top-notch. You can use the app to track your progress and get information on snow conditions. There are also webcams available to keep you informed.

    The average annual snowfall is 280 inches. The highest peak, Palmyra Peak, offers a unique 2,000 foot couloir. There are also several double black diamond runs.

    While Telluride does not have many day-trippers, it is well worth a visit on a powder day. Although the lift ticket prices are high, Telluride offers free lift tickets for children under five.

    The best time to visit Telluride is in the latter half of March. This is when the slopes receive the highest snow-to-people ratio. This is also when the snow is freshest. It's also a great time to check out lodging deals. Homes in the mountain Village are available for $2,000 or more per night in February and March.

    Cadmium telluride (CdTe) is a black, cubic crystalline powder. It is used as a semiconductor, infrared optical window, and solar cell material. Its properties are similar to those of zinc selenide. It is also used for spectroscopic analysis and g -ray detectors. It is toxic if ingested.

    Dec 08
    2022
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